Originally posted by Jayomu
Don't think it's a problem with the ps3 Bluetooth adapter, cuz all other controllers are working fine.
and the controller has to be fine otherwise it wouldn't work at all. the controller does not communicate over the usb when plugged in.
making it look for sure like the battery is the problem.
i have seen this behaviour occur at other times also. if you power down the ps3 using the menu "turn off system" with the controller on and plugged in and it shuts off the ps3 as normal, if you then switch it on via the power button the controller can fail to sync and only work with the controller plugged in.